pH, Conductivity and Ionselectiv Measurements sensION+ portable meters are compact, ... pH 2,00/4,01 /7,00 and 10,00 at 25C Manual calibration using the buffer solution of ... pH-meter EC7 Benchtop ...

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www.bergmanlabora.seDITT LAB - VÅRT JOBB pH, Conductivity and Ionselectiv Measurements BergmanLabora AB • Box 705 182 17 Danderyd • Tel: 08-625 18 50 • Fax: 08-625…

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www.bergmanlabora.seDITT LAB - VÅRT JOBB pH, Conductivity and Ionselectiv Measurements BergmanLabora AB • Box 705 182 17 Danderyd • Tel: 08-625 18 50 • Fax: 08-625 18 70 • info@bergmanlabora.se • www.bergmanlabora.se 2 Hach sensION+ portable meters are compact, rugged lightweight, and ideally suited for field measurements. Portable Meters Hach sensION+ SensION+ Portable Meters Waterproof IP67, shock resistant housing• Large backlit graphic screen with icon navigation• Simultaneous display of various parameters• Combined electrodes with built-in temperature probe and watertight connector• Carrying case designed to be a portable laboratory!• SensION+ portable meters, technical specifications PORTABLE METERS Measuring ranges pH: -2.00 to 19.99 mV: +/- 1400 Conductivity: 0.01μS/cm to 500 ms/cm TDS: 0 mg/l to 500 g/l Salinity: 0 to 50 g/l NaCl Dissolved Oxygen Saturation: 0 to 250 % (25°C) Concentration 0 to 22 mg/l (25°C) Temperature: -20 to 150°C (0 to 50°C for DO) Temperature compensation Automatic thanks to the Pt 1000 built-in in the probes. Temperature correction for conductivity Linear correction factor from 0 to 9,99 %/°C (default value 2 %) Reference temperature 20 or 25°C TDS conversion factor 0 to 4,44 (default value 0,64) Measuring mode Upon stabilisation or continuous Calibration pH 1,2 or 3 calibration points Automatic recognition of buffer solutions pH 2,00/4,01 /7,00 and 10,00 at 25°C Manual calibration using the buffer solution of your choice Restore factory calibration option mV Automatic recognition of a standard solution 220 mV at 25°C Manual calibration using the standard solution of your choice Restore factory calibration option Conductivity 1,2 or 3 calibration points Stored calibration solutions 147 μS/cm, 1413 μS/cm, 12,88 mS/cm and 111,8 mS/cm at 25°C Manual calibration using the standard solution of your choice Restore factory calibration option Dissolved Oxygen 1 or 2 calibration points Manual calibration at 0 and 100 % saturation Temperature adjustment Drift correction of the temperature probe at 25° and 85°C Display LCD with backlight Simultaneous display of several parameters Icon navigation Power supply 3 x AA batteries, battery life depends on model, above 500 hours for pH-meter Automatic switch off after 5 min. (this function can be disabled) Connection Watertight electrode connector MP-5 (5 contacts) for PH1 / EC5 MP-8 (8 contacts) for MM150 Meter housing features ABS, waterproof IP67 Dimensions 186 x 73 x38mm Weight 300 g Working environment Working T°: 0 to 50°C Storage T°: -15 to 65°C Relative humidity rate BergmanLabora AB • Box 705 182 17 Danderyd • Tel: 08-625 18 50 • Fax: 08-625 18 70 • info@bergmanlabora.se • www.bergmanlabora.se 3 Electrodes for SensION+ Portable Meters Specifications Combined pH General use Combined pH waste water Combined pH Low conductivity high temperature Combined pH puncture type Combined pH puncture type Model 5050T 5051T 5052T 5053T 5054T Special feature Gel With working protector open junction With working protector PTFE junction Built-in T° probe 2 junctions Removable steel knife,Built-in T° Measuring range 0 to 14 pH 2 to 14 pH 0 to 14 pH 2 to 14 pH 2 to 14 pH Temperature range 0 to 80 °C 0 to 80 °C 0 to 100 °C 0 to 60 ° C 0 to 60 °C Temperature probe Pt1000 Pt1000 Pt1000 Pt1000 Pt1000 Dimensions (under head) 12 mm x 85 mm 12 mm x 85 mm 12 mm x 85 mm 12 mm x 85 mm 12 mm x 85 mm Sensitive component Glass Glass Glass Glass Glass Body material Polycarbonate Glass Glass Stainless steel Stainless steel Filling Gel Solid Gel Solid Solid Connector MP-5 MP-5 MP-5 MP-5 MP-5 Cable length 1 m 1 m 1 m 1 m 1 m Product number LZW5050T.97.002 LZW5051T.97.002 LZW5052T.97.002 CRI5053T.99 CRI5054TC.99 PORTABLE METERS Specifications Conductivity General use Conductivity Difficult samples Multi* Multi* Model 5060 5062 5048 5059 Special feature - Rugged titanium body pH/Conductivity/ORP pH/Conductivity Measuring range 0,2 μS/cm up to 200 mS/cm 5 μS/cm up to 50 mS/cm 0 to 14 pH 25-200 mS/cm +/- 2000 mV 0 to 14 pH 5 μS/cm to 30 mS/cm +/- 2000 mV Temperature range 0 to 80 °C 0 to 80 °C 0 to 80 °C 0 to 80 °C Temperature probe Pt1000 Pt1000 Pt1000 Pt1000 Dimensions (under head) 12 mm x 85 mm 12 mm x 85 mm 12 mm x 85 mm 12 mm x 85 mm Sensitive component Platinum Platinum pH: Glass Cond & Redox: Platinum pH: Glass Cond: Titanium Body material Polycarbonate Titanium Polycarbonate Polycarbonate Filling - - Gel Gel Connector MP-5 MP-5 MP-8 MP-8 Cable length 1 m 1 m 1 m 1 m Product number LZW5060.97.0002 LZW5062.97.0002 LZW5048.97.0002 LZW5059.97.0002 *Only compatible with sensION+ multimeter MM150 BergmanLabora AB • Box 705 182 17 Danderyd • Tel: 08-625 18 50 • Fax: 08-625 18 70 • info@bergmanlabora.se • www.bergmanlabora.se 4 Hach sensION+ Benchtop Meters are designed to be all-in-one working stations, ready for a wide variety of applications, and come complete with integrated electrode holder and magnetic stirrer. Benchtop Meters Hach sensION+ SensION+ Benchtop Meters Housing and keyboard splashproof IP42• Large graphic display with backlight• Electrode parking positions• Colour coded calibration flasks with magnetic rod• Electrode holder fitted with a safe cable fastener• Built-in magnetic stirrer controlled from the instrument• BENCHTOP METERS Parameters PH3 Benchtop pH- meter PH31 GLP Benchtop pH-meter EC7 Benchtop conductivity meter EC71 GPL Benchtop conductivity meter MM374 GLP Benchtop multimeter Temperature x x x x x pH x x x Conductivity x x x Resistivity x x Salinity x x x TDS x x ORP/Redox x x x Nitrates x Fluoride x Sodium x Chloride x Ammonium x Ammonia x Specifications No of measuring channels 1 1 1 1 2 GLP functions x x x PC or printer output x x x Product number LPV2000.98.0002 LPV2100.98.0002 LPV3010.98.0002 LPV3110.98.000 LPV4110.98.0002 BergmanLabora AB • Box 705 182 17 Danderyd • Tel: 08-625 18 50 • Fax: 08-625 18 70 • info@bergmanlabora.se • www.bergmanlabora.se 5 SensION+ benchtop meters, technical specifications Measuring ranges pH: -2.00 to 19.99 mV: +/- 2000 Conductivity: 0,01/0.001*μS/cm up to 500/1000** ms/cm (*with Constant=0,1 cm-1, **with Constant=10 cm-1) Resistivity: 0 to 100 MOhms TDS: 0 mg/l to 500 g/l Salinity: 5,85 mg/l to 311,1g/l NaCl ISE: 10-5 M to 10-1 M Temperature: -20 to 150°C Temperature compensation Automatic with Pt 1000 or 10 kOhms temperature probe Manual if no T° sensor connected. Temperature correction for conductivity Linear correction factor from 0 to 9,99%/°C (default value 2%) Correction factor for natural waters following UNE EN 27888 – Except EC7 Reference temperature 20 or 25°C TDS conversion factor 0 to 4,44 (default value 0,64) Calibration Adjustable calibration alarm Automatic rejection of electrodes in poor condition pH 1,2 or 3 calibration points Automatic recognition of buffers among following series: • pH 2,00/4,01/7,00 and 10,00 at 25°C) • pH 1,679/4,006/6,865/7,00/9,18/10,012/12,454 at 25°C - Except PH3 Series of 3 free selectable buffer values - Except PH3 Manual calibration using any value -Except PH3 Manual entry of calibration results - Except PH3 Restore factory calibration option mV Automatic recognition of a standard 220 mV at 25°C Manual calibration using any value - Except PH3 Manual entry of calibration values - Except PH3 Restore factory calibration option - Except PH3 Conductivity 1, 2 or 3 calibration points Selection of standards in the following series • Molar 147 μS/cm, 1413 μS/cm, 12,88 mS/cm, 111,8 mS/cm at 25°C • Demal 1049 μS/cm, 12,85 mS/cm, 111,31 mS/cm at 25°C – Except EC7 • NaCl 1014,9 μS/cm for salinity Manual calibration using any value – Except EC7 Manual entry of the cell constant Restore factory calibration option Ionmetry (ISE) 2 to 5 calibration points Series of 5 user’s selectable calibration solutions Storage of 4 calibration curves Temperature adjustment Drift correction of the temperature probe at 25° and 85°C - Except PH3 and EC7 Measuring mode Upon stabilisation, continuous or by time - Except PH3 and EC7 2 independant measuring channels for MM340 and MM374 GLP functions – Except PH3 and EC7 340 results stored for each channel and 9 calibration results Date/Time, sample ID, user ID Connections Combined/indicator electrode: BNC Reference electrode: banana 5 mm Conductivity cell: 8 contact telephone plug T°: 5 mm banana or 4 contact telephone plug Data transfer – Except PH3 and EC7 RS232 output for PC or printer RS232 – USB adapter as option Display LCD graphic with backlight Menu available in French, English, Spanish, German, Portuguese Power supply Mains adapter 100-240 VAC (0,4 A/47-63 Hz) BergmanLabora AB • Box 705 182 17 Danderyd • Tel: 08-625 18 50 • Fax: 08-625 18 70 • info@bergmanlabora.se • www.bergmanlabora.se 6 Electrodes Maintenance Electrode Visually inspect the electrode. If there are bubbles in the bottom of the electrode, spin the electrode around by holding • the cord. This will push the liquid into the lower part of the electrode rod. Control the crystal level in the electrode. If too high: liquid in the electrode should be emptied, the crystals rinsed with • distilled water and the electrode refilled with fresh KCl solution. If too low: fill with saturated KCl or fresh KCl crystals. Clean the electrode regularly with Renovo N (Renovo x if fat samples are measured).• To ensure accurate results avoid contact with the bottom of the cup during measurement.• Keep the electrode in pH 4 buffer overnight (not colored). Please note that this will lead to higher dissolving of the • crystals. Rinse electrode with distilled water between samples. If an electrode is stored in KCl (new electrode), it must be • soaked in buffer pH 4 for at least 2 hours before use. Check the electrode’s instructions as storage and activation recommendations may differ between electrodes. Conductivity Cell Clean platinum-coated conductivity cells gently, aggressive cleaning may lead to degradation of the platinum surface • layer. Rinse the cell with deionized water between sample measurements. If fat samples have been measured, the cell can • first be cleaned with solvents that dissolve the sample (for example ethanol and acetone). Finish by washing the cell with water. If deposits occur on the cell surface, it can be dipped in Renovo N (cleaning kit from Radiometer) for 1h and then be • cleaned with deionized water. For short-term storage, the cell can be stored in deionized water.• For long-term storage, the cell can be kept dry, or placed in deionized water. After long-term storage, the electrode • needs to be placed in deionized water for 8 hours before use. Do not touch the shiny surface of the platinum-coated cells.• To clean the platinum cells, dip the cell in deionized water several times. Do not rinse it with excessive water pressure. • The pressure may lead to a part of the platinum layer being rinsed off, this will affect the cell-constant and lead to incorrect measurement results. MAINTENANCE BergmanLabora AB • Box 705 182 17 Danderyd • Tel: 08-625 18 50 • Fax: 08-625 18 70 • info@bergmanlabora.se • www.bergmanlabora.se 7 Radiometer Analytical’s unique Red Rod Technology provides not only fast response time but also long-term accuracy and reproducibility. Red Rod Electrodes Radiometer Analytical - Hach Lange Features: Reproducible measuring conditions ensured by the special bayonet head. The electrode fits into place in one easy movement and is fixed safely and securely in the same position for every measurement. Wide temperature range (0 to 100°C) thanks to fast temperature response of Red Rod Technology. Trouble-free liquid junction as Red Rod encapsulation of reference elements means no silver ions and therefore less risk of clogging. Fast and accurate response thanks to the symmetrical electrode chain formed by the internal and external Red Rod reference elements. Stable signal as the Red Rod Technology protects the reference elements from light interference. Saturated KCI salt-bridge aids stable liquid junction potential. The symmetry of Red Rod electrodes means that the iso pH is the same as the zero pH which provides highly reproducible results even when temperature fluctuations occur. The figure compares the measurements performed with a general-purpose Red Rod electrode and a traditional combined electrode. A MeterLab setup was used to measure certified standard pH solutions, pH 7.000 thermostated at 50°C and pH 4.005 thermostated at 25°C. The figure shows the fast response of the Red Rod electrode to changes in pH and temperature (curves offset to increase readability). ELECTRODES Your guarantee of reproducible results Red Rod combined pH electrode compared to traditional combined pH electrode 6,8 6,3 5,8 5,3 4,8 4,3 3,8 0 10 20 30 40 50 60 70 pH Time (minutes) Traditional technology Red Rod technology BergmanLabora AB • Box 705 182 17 Danderyd • Tel: 08-625 18 50 • Fax: 08-625 18 70 • info@bergmanlabora.se • www.bergmanlabora.se 8 The Right Electrode for your Application Combined pH electrodes ELECTRODES There is a Radiometer Analytical electrode for every application. The above table gives examples of the many applications for which Radiometer Analytical electrodes can be used. Where possible, choose an electrode which is “Recommended” but where one electrode is required for several applications, it may be necessary to select one which is “Acceptable”. Full specifications of the electrodes featured in the table are given on the following pages. In addition to your application, there are other considerations when choosing an electrode. The length and diameter obviously depend on the sample size and Applications PH C 20 01 pH C 20 02 pH C 20 03 pH C 20 05 pH C 20 11 pH C 20 15 pH C 20 51 pH C 20 85 pH C 24 01 pH C 24 41 pH C 25 01 pH C 26 01 pH C 27 01 pH C 30 01 pH C 30 05 pH C 30 06 pH C 30 06 L pH C 30 11 Alkaline solutions Aqueous solutions Blood Education purposes Emulsions Fat/cream/cosmetics Field use Gel electrode Hops/beer Hydrofluoric acid Lacquer Liqueur etc. Long length >150 mm Low ionic strength Microsamples Milk Non-aqueous media Oil Paint Paper Penetration (cheese) Photo baths Sea water, swimming pools Soil Solids, high content of Suspensions Temperature, high or varying Temperature sensor, built-in TRIS buffer Viscosity, high Voltammetry Yogurt, curdled milk sample vessel. Radiometer Analytical offers electrodes with various lengths for specialist applications and small diameters for microsamples. Risk of damageAcceptableRecommended Not Recommended BergmanLabora AB • Box 705 182 17 Danderyd • Tel: 08-625 18 50 • Fax: 08-625 18 70 • info@bergmanlabora.se • www.bergmanlabora.se 9 Combined pH electrodes Reference electrodesGlass electrodes When measuring at high temperatures, the electrochemical system within the electrode needs to be considered. Radiometer Analytical offers Ag/AgCl electrodes specially designed for high temperature measurements. To avoid chloride interference, a reference ELECTRODES electrode with a chloride-free reference system must be used (e.g. Hg/Hg2SO4 with K2SO4 salt-bridge) or a reference electrode with a double salt-bridge construction. Applications pH C 30 31 pH C 30 81 pH C 31 05 pH C 31 31 pH C 33 59 XC 16 1 PH G 20 0 pH G 20 1 pH G 21 1 pH G 30 1 pH G 31 1 XG 25 0 R EF 20 0 R EF 20 1 R EF 25 1 R EF 32 1 R EF 36 1 XR 82 0 Alkaline solutions Aqueous solutions Blood Education purposes Emulsions Fat/cream/cosmetics Field use Gel electrode Hops/beer Hydrofluoric acid Lacquer Liqueur etc. Long length >150 mm Low ionic strength Microsamples Milk Non-aqueous media Oil Paint Paper Penetration (cheese) Photo baths Sea water, swimming pools Soil Solids, high content of Suspensions Temperature, high or varying Temperature sensor, built-in TRIS buffer Viscosity, high Voltammetry Yogurt, curdled milk Risk of damageAcceptableRecommended Not Recommended BergmanLabora AB • Box 705 182 17 Danderyd • Tel: 08-625 18 50 • Fax: 08-625 18 70 • info@bergmanlabora.se • www.bergmanlabora.se 10 To meet your analysis needs, combined pH electrodes are available with a variety of lengths, diameters and reference systems. All our electrodes are delivered with a Certificate of Conformity signed by the Total Quality Manager. This specifies the sensitivity, zero pH, response time and batch number of the electrode. You may need a cable or plug adapter to connect your chosen electrode to your meter. Combined pH Electrodes Radiometer Analytical - Hach Lange ELECTRODES Temperature Sensors Type T101 T201 T202 T203 Part no. E51M003 E51M001 E51M002 E51M008 Temperature range -10 – 105°C -10 – 105°C -10 – 105°C -10 -105°C Diameter (mm) 7.5 7.5 7.5 7.5 mm Material Glass Glass Glass Glass Connection PYE Cinch Cinch RJ9 Instrument PHM83/85 ION83/85 CDM83 PHM2XX CDM2XX PHM9X PHM2XX CDM2XX PHM9X SensION+ For pH measurements and measurements with ion-selective electrodes and conductivity cells, use of a temperature sensor is recommended because temperature affects the results. BergmanLabora AB • Box 705 182 17 Danderyd • Tel: 08-625 18 50 • Fax: 08-625 18 70 • info@bergmanlabora.se • www.bergmanlabora.se 11 Radiometer pH Electrodes Applications General purpose Alkaline samples Model pHC2001 pHC2002 pHC2003 pHC2401 pHC2005 pHC2085 pHC2011 pHC2015 Probe part no. BNC E16M313 E16M315 E16M334 E16M400 E16M500 E16M345 E16M317 E16M318 Probe part no. Type 7 E16M336 E16M337 Combination probe YES YES YES YES YES YES YES YES Reference system Red Rod Red Rod Red Rod Red Rod Red Rod Red Rod Red Rod Red Rod Liquid junction Porous pin Porous pin Porous pin Annular ring Porous pin Porous pin Porous pin Porous pin pH range 0 12 0 -12 0 -12 0 -12 0 -12 0 -12 0 -14 0 -14 Temperature included NO NO NO NO NO YES NO NO Temperature range -10 -100°C -10 -100°C -10 -100°C -10 -100°C -10 -100°C -10 -100°C 0 -100°C 0 -100°C Diameter 12 mm 12 mm 12 mm 12 mm 12 mm 12 mm 12 mm 12 mm Minimum sample depth 18 mm 18 mm 18 mm 14 mm 14 mm 14 mm 18 mm 14 mm Special features ― Long Long ― Robust Temp. sensor ― Robust Salt-bridge solution Sat. KCl Sat. KCl Sat. KCl Sat. KCl Sat. KCl Sat. KCl Sat. KCl Sat. KCl *Screw cap electrode. Requires CL114 connection cable (part no. A94L114) for sensION+ meter compatibility Applications Surface measurement Soils Cl-sensitive samples Viscous samples High KCl flow General purpose Model pHC2441 pHC2051 pHC2501 pHC2601 pHC2701 pHC3001 pHC3081 Probe part no. BNC E16M320 E16M319 E16M321 E16M322 E16M323 E16M300 E16M301* E16M344 Probe part no. Type 7 E16M339 Combination probe YES YES YES YES YES YES YES Reference system Red Rod Red Rod Red Rod Red Rod Red Rod Ag/AgCl Ag/AgCl Liquid junction Annular ring Porous pin Double/Porous Sleeve Annular ring Porous pin Porous pin pH range 0 -12 0 12 0 -12 0 -12 0 -12 0 -12 0 -12 Temperature included NO NO NO NO NO NO YES Temperature range -10 -100°C -10 -100°C -10 -100°C -10 -100°C -10 -100°C 0 -80°C 0 -80°C Diameter 12 mm 12 mm 12 mm 12 mm 12 mm 12 mm 12 mm Minimum sample depth flat 18 mm 18 mm 18 mm 14 mm 18 mm 18 mm Special features ― ― ― ― ― ― Temp. sensor Salt-bridge solution Sat. KCl Sat. KCl Sat. KCl Sat. KCl Sat. KCl 3 M KCl + sat. AgCl BergmanLabora AB • Box 705 182 17 Danderyd • Tel: 08-625 18 50 • Fax: 08-625 18 70 • info@bergmanlabora.se • www.bergmanlabora.se 12 Radiometer pH Electrodes Applications General purpose General purpose General purpose Alkaline samples Alkaline samples General purpose Model pHC3006 pHC3006L pHC3005 pHC3011 GK2401B GK2401C Probe part no. BNC E16M306* E16M307* E16M302BNC E16M303* E16M324* Probe part no. Type 7 945-261 945-252 Combination probe YES YES YES YES YES YES Reference system Ag/AgCl Ag/AgCl Ag/AgCl Ag/AgCl Red Rod Red Rod Liquid junction Porous pin Porous pin Porous pin Porous pin Porous pin Porous pin pH range 0 -12 0 - 12 0 - 12 0 - 14 0 - 14 0 - 14 Temperature range 0 - 80°C 0 - 80°C 0 - 80°C 0 - 80°C 0 - 100°C -10 - 100°C Lower diameter 6.5 mm 6.5 mm 12 mm 12 mm 9,5 mm 9,5 mm Minimum sample depth 14 mm 14 mm 12 mm 18 mm 16 mm 16 mm Special features Small Ø Long, small Ø Robust ― ― ― Salt-bridge solution 3 M KCl + sat. AgCl 3 M KCl + sat. AgCl 3 M KCl + sat. AgCl 3 M KCl + sat. AgCl Sat. KCl Sat. KCl Applications Microsamples Microsamples General-purpose Gel-filled Penetration Gelfilled Penetration Model XC161 pHC3359 pHC3105 pHC3131 pHC3031 Probe part no. B10C161* E16M343BNC E16M308* E16M328* E16M325* Combination probe YES YES YES YES YES Reference system Ag/AgCl Ag/AgCl Ag/AgCl Ag/AgCl Ag/AgCl Liquid junction Porous pin Fibre Opening Opening Porous pin pH range 0 - 12 0 - 12 2 - 12 2 - 12 0 - 12 Temperature included NO NO NO NO NO Temperature range 0 - 80°C 0 - 80°C 0 - 80°C 0 - 80°C 0 - 80°C Lower diameter 5 mm 3 mm 12 mm 8 mm 8 mm Minimum sample depth 8 mm 2 mm 18 mm 14 mm 14 mm Special features ― ― Robust ― ― Salt-bridge solution 3 M KCl + sat. AgCl 3 M KCl + sat. AgCl Solid gel (3 M KCl) Solid gel (3 M KCl) 3 M KCl + sat. AgCl ELECTRODES *Screw cap electrode. Requires CL114 connection cable (part no. A94L114) for sensION+ meter compatibility BergmanLabora AB • Box 705 182 17 Danderyd • Tel: 08-625 18 50 • Fax: 08-625 18 70 • info@bergmanlabora.se • www.bergmanlabora.se 13 Single and combined metal electrodes can be used for redox measurements, redox titrations or potentiometric techniques hereas double metal electrodes are ideal for imposed current potentiometric titration. Radiometer Analytical’s electrode range features single, double and combined metal electrodes with latinum, silver, gold, antimony and glassy carbon sensing elements. Metal and Combined Metal Electrodes Radiometer Analytical - Hach Lange ELECTRODES Metal Electrodes and Combined Metal Electrodes Applications General- purpose Karl Fischer titrations Redox meas. Silver halides Titra- tion pH meas. titration Redox meas. Type M241Pt M231Pt M231Pt2 MC3051Pt M295Ag M291Ag MC2095Sb MC201Au-8 Part no. E31M001 E31M002* E32M001 E31M003* E34M003 E34M002* E36M001 E36M005 Sensing element Platinum plate 5 x 5 mm Platinum wire Ø 1 mm 2 platinum wires Ø 1 mm Platinum ring Silver rod Silver rod Antimony rod Gold wire Ø 1 mm Temperature range -10 – 100°C -10 – 100°C -10 – 100°C 0 – 80°C -10 – 100°C 0 – 80°C 0 – 60°C -10 – 100°C Lower diameter 7.5 mm 8 mm 12 mm 12 mm 7.5 mm 8 mm 12 mm 12 mm Reference system Ag/AgCl Hg/Hg2SO4 Red Rod Liquid junction Porous pin Porous pin Porous pin Connection Banana plug Screw cap 2 x banana Screw cap Banana plug Screw cap BNC plug BNC plug Salt-bridge solution 3 M KCl with sat. AgCl Sat. K2SO4 Sat. KCl Minimum sample depth 18 mm 18 mm 18 mm 14 mm 18 mm 14 mm Special features ― Long Long ― ― Robust Salt-bridge solution Sat. KCl Sat. KCl Sat. KCl Sat. KCl Sat. KCl Sat. KCl Recommended Reference Electrode ― ― ― ― ― ― *Screw cap electrode. Requires CL114 connection cable (part no. A94L114) for sensION+ meter compatibility Applications Voltammetry Voltammetry Redox Type XM110 XM120 XM140 XM150 M291C Part no. B35M110* B35M120* B35M140* B35M150* E36M003* Sensing element Platinum wire Ø 1 mm Platinum plate 5 x 5 mm Platinum plate 8 x 8 mm Platinum disc Ø 10 mm Glassy carbon rod Ø 3 mm Temperature range -10 – 100°C -10 – 100°C -10 – 100°C -10 – 100°C 0 – 60°C Diameter 8 mm 8 mm 8 mm 12 mm 8 mm Connection Screw cap Screw cap Screw cap Screw cap Screw cap BergmanLabora AB • Box 705 182 17 Danderyd • Tel: 08-625 18 50 • Fax: 08-625 18 70 • info@bergmanlabora.se • www.bergmanlabora.se 14 pH glass electrodes from Radiometer Analytical are made with highly shock-resistant glass, making them extremely tough. The average lifetime of a correctly maintained glass pH electrode is approximately 2 years. Certain electrodes are made with special glass for pH measurements in strongly alkaline solutions. These electrodes allow measurements within the 0 - 14 pH range without significant deviation from the theoretical response. Glass pH electrodes are always used in combination with reference electrodes. The zero pH of Red Rod glass pH electrodes when used with their recommended reference electrode is approximately pH 6.65. The zero pH of glass pH electrodes is approximately pH 6.65 when measured against a calomel reference electrode (e.g. REF421, XR110) and approximately pH 7.25 when measured against an Ag/AgCl reference electrode (e.g. REF321). Glass pH Electrodes Radiometer Analytical Glass pH electrodes ELECTRODES Applications Microsamples General-purpose Alkaline samples General purpose Alkaline samples Alkaline samples Model pHG200 pHG201 pHG211 pHG301 pHG311 XG250 Probe part no. E11M002BNC E11M006BNC E11M003BNC E11M001* E11M004* B10B250* Combination probe NO NO NO NO NO NO Reference system Red Rod Red Rod Red Rod Ag/AgCl Ag/AgCl Ag/AgCl Liquid junction ― ― ― ― ― ― pH range 0 - 12 0 - 12 0 - 14 0 - 12 0 - 14 0 - 14 Temperature included NO NO NO NO NO NO Temperature range 10 - 100°C -10 - 100°C 10 - 100°C 0 - 80°C 0 - 80°C 0 - 80°C Lower diameter 4 mm 7.5 mm 7.5 mm 12 mm 12 mm 10 mm** Minimum sample depth 4 mm 7 mm 7 mm 12 mm 12 mm 12 mm Special features ― ― ― ― ― ― Salt-bridge solution ― ― ― ― ― ― Recommended Reference Electrode REF200 REF201/251 REF201 for general use REF201/251 REF201 forgeneral use REF321 REF321 BergmanLabora AB • Box 705 182 17 Danderyd • Tel: 08-625 18 50 • Fax: 08-625 18 70 • info@bergmanlabora.se • www.bergmanlabora.se 15 During measurement, the salt-bridge junction (also called liquid junction protection tube) prevents the reference electrode from being contaminated by the media and vice-versa. It consists of a glass tube terminated by a liquid junction. Always ensure the filling solution used corresponds to the application. A reference electrode provides a stable potential whatever the measurement conditions. The main differences between reference electrodes are the type of reference system and the liquid junction. Radiometer Analytical offers electrodes using both Red Rod and traditional technology. Electrodes with a double junction are mostly designed for measurements using ion-selective electrodes or samples sensitive to Cl- or K+. Sleeve junctions have a high flow to prevent the risk of clogging. Porous pins are used for general applications. Fibre reference electrodes have a slow flow to avoid contamination of the media. Reference Electrodes Radiometer Analytical Salt-bridge junctions Reference Electrodes *Screw cap electrode. Requires CL114 connection cable (part no. A94L114) for sensION+ meter compatibility Applications Micro-samples General purpose General purpose General purpose Non-aqueous media Voltammetry Impedance Model REF200 REF201 REF251 REF321 REF361 XR300 XR820 Probe part no. E21M008 E21M009 E21M001 E21M002* E21M003 B20B300* B20C820* Reference system Red Rod Red Rod Red Rod Ag/AgCl Ag/AgCl Ag/AgCl Ag/AgCl Liquid junction Porous pin Porous pin Porous pin / porous pin Porous pin Glass sleeve Porous pin Porous pin / fibre Temperature range -10 -100°C -10 -100°C -10 -100°C -5 -80°C -5 -80°C -5 -80°C -5 -80°C Lower diameter 4 mm 7.5 mm 12 mm 8 mm 12 mm 8 mm 8 mm Special features For use with pHG200 ― Double junction ― ― ― ― Salt-bridge solution Sat. KCl Sat. KCl Sat. KCl 3 M KCl with sat. AgCl 3 M KCl with sat. AgCl Sat. KCl + sat. AgCl Sat. KCl + sat. AgCl upper res. ELECTRODES Type AL100 AL110 AL120 Part no. B40A520 B40A550 B40A610 Lower diameter 12 mm 8 mm 8 mm Junction Ceramic Ceramic Ceramic Special features for Ø7.5 or 8 mm ref. electrodes for ref. electrodes with ground joint BergmanLabora AB • Box 705 182 17 Danderyd • Tel: 08-625 18 50 • Fax: 08-625 18 70 • info@bergmanlabora.se • www.bergmanlabora.se 16 The use of ion-selective electrodes constitutes a quick and cost- effective method of determining ionic activity. Due to their quality and diversity, Radiometer Analytical ion- selective electrodes efficiently solve various analytical problems of species in solution. Each electrode is carefully checked before packing and is delivered with an individual control report including information such as the response curve, checkpoint value and slope. Ion-selective Electrodes Radiometer Analytical - Hach Lange ELECTRODES Ion-selective Electrodes Ion Species Br - Ca ++ Cl - Cl - CN - Cu ++ F - Model ISE25Br ISE25Ca ISE25Cl ISE/HS25Cl ISE25CN ISE25Cu ISE25F Probe part no. E41M001* E41M002* E41M003* E41M004* E41M005* E41M006* E41M007* Combination probe Concentration range (M) 10 -6 -100 2 x 10 -6 -100 5 x 10 -5 -100 10 -6 -100 5 x 10 -7 -10 -3 10 -6 -100 5 x 10 -7 -100 Concentration range (ppm) 0.08 -80000 0.1 -40000 1.8 -35000 0.04 -35000 0.013 -25 0.06 -60000 0.01 -20000 Temperature range 0 -60°C 0 -50°C 0 -60°C 0 -60°C 0 -60°C 0 -60°C 0 -60°C Diameter 12 mm 12 mm 12 mm 12 mm 12 mm 12 mm 7 mm pH range 2 -14 4 -12 2 -14 2 -4 9 -14 0 -14 5 -11 Sensor type Solid-state PVC membrane Solid-state Solid-state Solid-state Solid-state Solid-state Interfering ions I -, S2-, CN -, SCN Zn2+, Pb2+ I -, CN -, Br -, SCN I -, CN -, Br -, SCN I -, Br -, S2 HgS, Ag+, Cl OH Recommended reference electrodes REF251 REF201 REF251 REF251 REF251 REF201 REF251 REF201 REF251 REF201 REF251 *Screw cap electrode. Requires CL114 connection cable (part no. A94L114) for sensION+ meter compatibility BergmanLabora AB • Box 705 182 17 Danderyd • Tel: 08-625 18 50 • Fax: 08-625 18 70 • info@bergmanlabora.se • www.bergmanlabora.se 17 Ion-selective Electrodes Ion Species F - I - K+ Na+ NH4 + NO3 - Pb++ Model ISEC301F ISE25I ISE25K ISE21Na ISE25NH4 ISE25NO3 ISE25Pb Probe part no. E41M017* E41M008* E41M009* E41M010* E41M013* E41M014* E41M015* Combination probe Concentration range (M) 5 x 10 -7 -100 10 -6 -10 -1 2 x 10 -6 -100 2 x 10 -6 -100 3 x 10 -6 -100 3 x 10 -6 -100 10 -6 -100 Concentration range (ppm) 0.01 -20000 0.13 -13000 0.08 -40000 0.04 -20000 0.06 -20000 0.2 -60000 0.2 -200000 Temperature range 0 -50°C 0 -60°C 0 -50°C 0 -70°C 0 -50°C 0 -50°C 0 -60°C Diameter 12 mm 12 mm 12 mm 12 mm 12 mm 12 mm 12 mm pH range 5 -7 2 -12 2 -12 5 -12 3 -8 3 -10 3 -7 Sensor type Solid-state Solid-state PVC membrane Glass PVC membrane PVC membrane Solid-state Interfering ions OH CN -, Hg2+, Br -, SCN NH4 +, Rb+ Li+, NH4 +, Rb+, Ag+ K+ Cl -, Br -, NO2 - Hg2+, Cu2+, Ag+ Recommended reference electrodes ― REF201 REF251 REF201 REF251 REF251 REF251 REF201 REF251 REF251 *Screw cap electrode. Requires CL114 connection cable (part no. A94L114) for sensION+ meter compatibility ELECTRODES BergmanLabora AB • Box 705 182 17 Danderyd • Tel: 08-625 18 50 • Fax: 08-625 18 70 • info@bergmanlabora.se • www.bergmanlabora.se 18 It is important to choose a cell with the right construction and geometry for your particular application and working conditions. Radiometer Analytical offers conductivity cells for a wide variety of applications. 2-pole cells have a traditional design based on two plates of platinum. They are ideal for routine measurement of conductivity and for use with a sample changer due to the easy rinsing. 3-pole cells consist of 3 platinum rings which facilitate optimal shielding during measurement. Conductivity Cells Radiometer Analytical ELECTRODES Conductivity Cells Applications General purpose General purpose General purpose General purpose General purpose Sample changer Resistant media Viscous Titration Model CDC536T CDC836T CDC641T CDC745-9 XE100 CDC741T CDC267-9 CDC241-9 Probe part no. RJ45 E61M021 E61M020 E61M022 E61M013* B60E100* E61M023 E61M011* E61M008* Probe part no. MAB6 B15B001 E61M012 Body material Epoxy1 Epoxy1 Glass Epoxy Glass Glass Glass Glass Cell constant (cm-1) 1.0 1.0 0.85 1.0 1.0 1.0 0.1 1.0 Number of poles 3 3 2 2 2 2 2 2 Platinised NO YES YES YES YES YES NO NO Temperature included YES YES YES NO NO YES NO NO Max. temperature 80°C 80°C 100°C 100°C 100°C 100°C 100°C 100°C Diameter 12 mm 12 mm 12 mm 12 mm 12 mm 12 mm 12 mm 12 mm Minimum sample depth 35 mm 35 mm 14 mm 14 mm 10 mm 10 mm 26 mm 10 mm *Screw cap electrode. Requires CL143connection cable (part no. A94L143) for sensION+ meter compatibility 1) removable epoxy tube for easy rinsing (can be replaced by glass tube) Conductivity measurement is temperature dependent (if the • temperature increases so does the conductivity value). When performing conductivity measurements, it is advisable to choose a cell with a built-in temperature sensor or use a separate sensor. Remember to calibrate your conductivity • cell regularly as the cell constant may vary due to changes in electrode surface due to contamination, for example. Some ti ps BergmanLabora AB • Box 705 182 17 Danderyd • Tel: 08-625 18 50 • Fax: 08-625 18 70 • info@bergmanlabora.se • www.bergmanlabora.se 19 Recommended conductivity cells by application Applications/Characteristics C D C 56 6T C D C 86 6T C D C 56 5 C D C 64 1T C D C 74 5- 9 XE 10 0 C D C 51 1T C D C 74 1T C D C 86 1T C D C 26 7- 9 C D C 24 1- 9 C D C 74 9 Wide conductivity range (general purpose) x x x x Various aqueous and non-aqueous media x x x Very strong acids and bases x Use with sample changer x Built-in temperature sensor x x x x x x Continuous measurements x x x Microsamples x Flow measurements x Titration x Salinity (high conductivity) x x Pure water x Meets requirements of USP 24-NF19 x x Meets requirements of EP 2.2.38 x Use in glass tubes x Plastic body x x x x x Viscous media x Highly resistant media x Field use x x x x Conductivity Cells Applications Generalpurpose General purpose General purpose General purpose Pure Water Strong acid basis Micro samples Type CDC566T CDC866T CDC565 CDC745-9 CDC511T CDC861T CDC749 Part no. MAB6 E61M010 E61M015 E61M003 E61M009 E61M016 E61M014 Part no. screw cap E61M013 Body Epoxy1) Epoxy1) Epoxy Epoxy TPX2) Glass Glass Cell. Constant (cm-1) 3) 1.0 1.0 1.0 1.0 1.0 1.0 1.7 Number of poles 4 4 4 2 4 4 2 Platinised NO YES NO YES NO YES YES Temperature sensor YES YES NO NO YES YES NO Diameter (mm) 12 mm 12 mm 12 mm 12 mm 12 mm 12 mm 4 mm Max. temperature 80°C 80°C 80°C 100°C 80°C 100°C 100°C Min. immersion depth 35 mm 35 mm 30 mm 14 mm 3 ml4) 35 mm 4 mm CDM210/CDM230 YES YES YES YES3) YES YES YES 1) Removable epoxy tube for easy rinsing (can be replaced by glass tube - see accessories) 2) Polymethylpentene. Removable part for easy rinsing ELECTRODES 3) The cell constant is determined experimentally for each cell and the value is given as a guideline only 4) Minimum sample volume BergmanLabora AB • Box 705 182 17 Danderyd • Tel: 08-625 18 50 • Fax: 08-625 18 70 • info@bergmanlabora.se • www.bergmanlabora.se 20 The use of standards manufactured by an accredited laboratory gives you complete confidence in the traceability chain and calculated uncertainties. Radiometer Analytical is part of the Hach Lange group whose Calibration Laboratory, located in Berlin, is accredited for the calibration of certified pH and conductivity standards by DKD, the German national accreditation authority. This accreditation (No. DKD-K-47901) is recognised in more than 35 countries. All standards are formulated in compliance with NIST, IUPAC and DIN19266 specifications (1 p. 21). IUPAC Series certified pH standards are fully traceable to the Standard Hydrogen Electrode through Certified Reference Material produced by the Primary Laboratory of either NIST or DFM (2 p. 21). Radiometer Analytical certified conductivity standards are fully traceable to SI units via Certified Reference Materials manufactured by NIST. They are prepared and calibrated according to the internationally recognised demal scale laid down by the International Organisation of Legal Metrology (OIML – Recommendation No. 56). Accredited Calibration Laboratory CERTIFIED STANDARDS ** The NaCl 25 certified conductivity standard comes in a 250 ml glass bottle. Radiometer Analytical certified standards are fully traceable. Certificates are always included with the buffer solutions. Type Value Qty Part No. KCl 1D 111.3 mS/cm ±0.5% at 25°C 500 ml S51M001 KCl 0.1D 12.85 mS/cm ±0.35% at 25°C 500 ml S51M002 KCl 0.01D 1408 μS/cm ±0.5% at 25°C 500 ml S51M003 NaCl 0.05% 1015 μS/cm ±0.5% at 25°C 500 ml S51M004 NaCl 25 25.0 μS/cm ±5% at 25°C 250 ml S51M013** Certified conductivity standards Type Qty Part No. pH4.01 250 ml LZW9463.99 pH7.00 250 ml LZW9464.98 pH10.00 250 ml LZW9471.99 Buffers for certified sensION+ * Radiometer Analytical formulation. Type Value Qty Part No. pH1.679 pH 1.679 ±0.010 at 25°C 500 ml S11M001 pH4.005 pH 4.005 ±0.010 at 25°C 500 ml S11M002 pH6.865 pH 6.865 ±0.010 at 25°C 500 ml S11M003 pH7.000* pH 7.000 ±0.010 at 25°C 500 ml S11M004 pH7.413 pH 7.413 ±0.010 at 25°C 500 ml S11M005 pH9.180 pH 9.180 ±0.010 at 25°C 500 ml S11M006 pH10.012 pH 10.012 ±0.010 at 25°C 500 ml S11M007 pH12.45 pH 12.45 ±0.05 at 25°C 500 ml S11M008 IUPAC Series certified pH standards Type Value Qty Part No. pH4.00 pH 4.00 at 25°C 500 ml S11M012 pH7.00 pH 7.00 at 25°C 500 ml S11M013 pH10.00 pH 10.00 at 25°C 500 ml S11M014 4-7-10 Series A B BergmanLabora AB • Box 705 182 17 Danderyd • Tel: 08-625 18 50 • Fax: 08-625 18 70 • info@bergmanlabora.se • www.bergmanlabora.se 21 Totally reliable packaging Each standard is delivered in an airtight can and is supplied with a film-wrapped Certificate of Conformityand Traceability as well as a DKD Calibration Certificate specifying the exact measured value and calculated expanded uncertainty (k=2) for each batch of pH and conductivity solution. (1) Except pH7.000 formulated by us according to NIST, IUPAC and DIN19266 specifications of pH6.865 and pH7.413. (2) Dansk Fundamental Metrologi A/S is accredited for pH measurements by the Danish Accreditation and Metrology Fund (DANAK) (no. 255). (3) 4-year guarantee for pH standards (2 years for pH 12.45). 2-year guarantee for conductivity standards (1 year for the 25 μS/cm). The guarantee is valid from the date of the Certificate of Conformity and Traceability and only applies to standards kept unopened in the sealed can in compliance with the storage recommendations specified in the certificate. Safe storage thanks to the airtight can. B International accreditation a DKD Calibration Certificate proves the traceability to national standards. GLP - right from the start the date of opening can be marked directly on the bottle. Recommended shelf life the observed typical shelf life after opening is printed on the bottle, ensuring timely use (2-3 months depending on the standards). A guaranteed value the nominal value of the standard is guaranteed until first opening, even after several years’ storage(3). GLP - every day the number of uses can be marked directly on the bottle in line with Good Laboratory Practice. A useful reference a pH or conductivity temperature dependence table is printed on the bottle. A Proven traceability each standard comes with its own Certificate of Conformity and Traceability. Accurate values the nominal value and the tolerance of pH standards are given with a resolution of 3 significant decimals. Glossary & useful links NIST National Institute of Standards and Technology www.nist.gov IUPAC International Union of Pure and Applied Chemistry www.iupac.org DFM Danish National Metrology Institute www.dfm.dtu.dk DKD Deutscher Kalibrierdienst www.dkd.eu DANAK Danish Accreditation and Metrology Fund www.danak.org OIML International Organisation of Legal Metrology www.oiml.org PACKAGING BergmanLabora AB • Box 705 182 17 Danderyd • Tel: 08-625 18 50 • Fax: 08-625 18 70 • info@bergmanlabora.se • www.bergmanlabora.se 22 Electrode Maintenance MAINTENANCE Reference element Solutions Red Rod KCl•L and KCl•C KS100 and KCl•C Ag/AgCl (pHC3xxx /REF3xx) KCl•Ag Ag/AgCl (XCxxx/ XRxxx) KS120 Calomel KCl•L and KCl•C KS100 and KCl•C Hg/Hg2SO4 KS160 Type Description Qty Part No. RENOVO•N Normal Cleaning Solution 250 ml S16M001 RENOVO•X Xtra Strong Cleaning Solution 250 ml S16M002 KS400 Pepsin in HCl Solution 250 ml C20C370 KS410 Thiourea Solution 250 ml C20C380 Type Description Qty Part No. KS100 Saturated KCl Solution 500 ml C20C300 KCl•L Saturated Solution of KCl 100 ml S21M002 KCl•L-30 Saturated Solution of KCl, 30 ml S21M010 KCl•C KCl Crystals 15 g S21M001 KCl•Ag 3 M KCl Solution Saturated with AgCl 100 ml S21M004 KCl•Ag-30 3 M KCl Solution Saturated with AgCl 30 ml S21M011 KS110 KCl Solution 3 M 500 ml C20C320 KS120 Saturated KCl + AgCl Solution 500 ml C20C310 KS120-30 Saturated KCl + AgCl Solution 30 ml S21M009 KS160 Saturated K2SO4 Solution 500 ml C20C500 KS160-30 Saturated K2SO4 Solution 30 ml S21M007 LiCl-30 1 M LiCl Solution 30 ml S21M008 Selecting the right filling solution Maintenance solutions Filling and storage solutions for combined and reference electrodes The maintenance requirements of electrodes vary according to the application. After measurements in aqueous solutions, cleaning with a mild solution such as RENOVO•N is sufficient. However, when the solutions contain protein, for example, stronger cleaning agents such as RENOVO•X or Pepsin in HCl are required. For junctions contaminated with sulphides or AgCl precipitate, Radiometer Analytical’s Thiourea Solution is ideal. The operating instructions provide cleaning instructions for each type of electrode. Maintenance solutions BergmanLabora AB • Box 705 182 17 Danderyd • Tel: 08-625 18 50 • Fax: 08-625 18 70 • info@bergmanlabora.se • www.bergmanlabora.se 23 Electrode plug Instrument socket Part no. BNC Type 7 A94P800 Type 7 BNC A94P802 2 x banana BNC A94P801 BNC DIN A94P806 BNC Banana A94P807 Banana Ø 4 mm Banana US Ø 2 mm X41V001 Banana Ø 4 mm Type 7 809-147 UHF MAB6 A94P001 MAB6 UHF+PYE A94P002 Plug adapters for screw cap electrodes Instrument socket Type Part no. Banana CL111 A94L111 P2 CL112 A94L112 DIN CL113 A94L113 BNC CL114 A94L114 Type 7 CL116 A94L116 UHF (PL259) CL119 A94L119 2 x banana CL120 A94L120 LEMO Ø 5 mm CL129 A94L129 MAB6 CL136 A94L136 Connection cables for screw cap electrodes Accessories ACCESSORIES KONTAKTA OSS! Analysinstrument Apparater Förbrukning lab Renrumsprodukter Mikroskopi / Optisk mätning Service BergmanLabora AB Tel: 08-625 18 50 Fax: 08-625 18 70 info@bergmanlabora.se www.bergmanlabora.se B L- LI A S -1 20 6 -1

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