ChemInform Abstract: The Photooxygenation of Benzyl, Heteroarylmethyl, and Allyl Sulfides.

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    06-Jun-2016

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  • 1999 oxidation, dehydrogenation, ozonolysis

    oxidation, dehydrogenation, ozonolysisO 0210

    41 - 040The Photooxygenation of Benzyl, Heteroarylmethyl, and Allyl Sul-fides. In aprotic solvents the title reaction offers a mild route to preparealdehydes. This is a general method which can be applied to benzyl derivativeswith either electron-donating or electron-withdrawing substituents. However,starting from -substituted sulfides some limitations are observed. In a proticsolvent (MeOH) sulfoxides are generally the main products. The mild conditionsand inertness of the pyridine sulfide (Ig) against N-oxidation are remarkable. (BONESI, SERGIO M.; TORRIANI, ROSANGELA; MELLA, MARIELLA;ALBINI, ANGELO; Eur. J. Org. Chem. (1999) 7, 1723-1728; Dip. Chim. Org.,Univ. Pavia, I-27100 Pavia, Italy; EN)

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