ChemInform Abstract: Oxime Palladacycle-Catalyzed Suzuki—Miyaura Alkenylation of Aryl, Heteroaryl, Benzyl, and Allyl Chlorides under Microwave Irradiation Conditions.

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  • ChemInform 2011, 42, issue 49

    Polyphenylalkene derivativesQ 0740 DOI: 10.1002/chin.201149087

    Oxime Palladacycle-Catalyzed SuzukiMiyaura Alkenylation of Aryl, Hetero-aryl, Benzyl, and Allyl Chlorides under Microwave Irradiation Conditions. The reaction applies a catalyst, generated in situ from (I) and tBu3PHBF4 and Bu4NOH as a co-catalyst and is general for various alkenyl boronic acids, potassium trifluorob-orates or pinacol boronic esters and aromatic, heteroaromatic, allylic and benzylic chlo-rides. The transformations proceed with high regioselectivities. (CIVICOS, J. F.; ALONSO*, D. A.; NAJERA, C.; Adv. Synth. Catal. 353 (2011) 10, 1683-1687, http://dx.doi.org/10.1002/adsc.201100019 ; Dep. Quim. Org., Univ. Alicante, E-03080 Alicante, Spain; Eng.) Y. Steudel

    49- 087 2011 Wiley-VCH Verlag GmbH & Co. KGaA, Weinheim

  • ChemInform 2011, 42, issue 49

    2011 Wiley-VCH Verlag GmbH & Co. KGaA, Weinheim

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